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    Total synthesis of (-)- and (+)-tedanalactam

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    J_Org_Chem_74_6378a.pdf (681.0Kb)
    Date
    2009
    Author
    Majik, M.S.
    Parameswaran, P.S.
    Tilve, S.G.
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    Abstract
    The first stereoselective route providing access to both enantiomers of tedanalactam, a naturally occurring piperidone, has been developed. The stereogenic centers were generated by the use of Sharpless asymmetric dihydroxylation. Tandem oxidation-Wittig reaction and one-pot deprotection, lactamization, and oxirane ring formation are the other key elements
    URI
    http://drs.nio.org/drs/handle/2264/3477
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