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dc.contributor.authorSingh, K.S.
dc.contributor.authorKaminsky, W.
dc.date.accessioned2011-01-04T07:01:11Z
dc.date.available2011-01-04T07:01:11Z
dc.date.issued2011
dc.identifier.citationInorganica Chimica Acta, vol.365(1); 2011; 487-491
dc.identifier.urihttp://drs.nio.org/drs/handle/2264/3768
dc.description.abstractA series of water soluble complexes of general formula [(Eta sup(6)-arene) Ru ((C sub(5) H sub(4) N) sub(2) CNRi) Cl) PF sub(6) have been prepared by the reaction of [[(Eta sup(6)- arene) RuCl sub(2)) sub(2)) with appropriate 2,2’-dipyridyl-N-alkylimine ligands (dpNRi) in the presence of NH sub(4) PF sub(6) (where; R = Me or Et; arene = p-cymene, C sub(6) Me sub(6), C sub(6) H sub(6)). The 2,2’-dipyridyl-N-alkylimine ligands are prepared by reaction of 2,2’-dipyridyl ketone with the corresponding alkylamine. The complexes are readily obtained as air stable yellow to dark brown solids by simple stirring at room temperature. The complexes are isolated as their hexafluorophosphate salts and characterized on the basis of spectroscopic data. The molecular structure of representative complex ((Eta sup(6)-Csub(6) Me sub(6)) Ru ((C sub(5) H sub(4) N) sub(2) C= N-Me) Cl) PF sub(6) has been determined by single crystal X-ray diffraction studies.
dc.language.isoen
dc.publisherElsevier
dc.rightsAn edited version of this paper was published by Elsevier. Copyright [2011] Elsevier
dc.subjectwater soluble complexes
dc.subjectRuthenium
dc.subjectDimethylpyridyl ketone
dc.subjectCrystal structure
dc.titleSynthesis, spectral and structural studies of water soluble arene ruthenium (II) complexes containing 2,2′-dipyridyl-N-alkylimine ligand
dc.typeJournal Article


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