dc.contributor.author | Singh, K.S. | |
dc.contributor.author | Kollipara, M.R. | |
dc.date.accessioned | 2011-07-29T07:26:11Z | |
dc.date.available | 2011-07-29T07:26:11Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | Journal of Indian Chemical Society, vol.88(4); 2011; 497-504 | |
dc.identifier.uri | http://drs.nio.org/drs/handle/2264/3883 | |
dc.description.abstract | Mono and di-nuclear eta sup (6)-p-cymene ruthenium(II) complexes containing carboxylato ligand of formulation [(eta sup (6)-p-cymene)Ru(pa)Cl] and [{(eta sup (6)-p-cymene)RuCl}2 (mu-LL)] [where, pa = O sub (2)CC sub (6)H sub (4)-p-OMe (1), LL = C sub (2)O sub (4)(7) or C sub (2)CH sub (2)O sub (4)(10)] have been prepared by the reaction of [(p-cymene)RuCl sub (2)]sub (2) with the corresponding sodium salts of the carboxylic acids. Treatment of (eta sup (6)-p-cymene) ruthenium(II) carboxylato complexes with NaN sub (3) yielded azido complex [{(eta sup (6)-p-cymene)Ru(mu-N sub (3))Cl} sub (2)] whereas halide scavengers such as silver acetate, silvertrifluroacetate leads to the substitution of chlorine to give neutral complexes of formulation [{(eta sup (6)-p-cymene)RuY} sub (2)(mu-LL)](where, LL = bidentate carboxylate, Y = MeCO sub (2) or CF sub (3)CO sub (2)). Mono and di-cationic complexes were also been prepared by the treatment of complex 1 with the corresponding neutral ligands in the presence of AgBF sub (4). The complexes were fully characterized on the basis of microanalysis, FT-IR and NMR spectroscopic data | |
dc.language.iso | en | |
dc.publisher | The Indian Chemical Society | |
dc.rights | Copyright [2011]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. | |
dc.subject | p-cymene | |
dc.subject | ruthenium | |
dc.subject | azide | |
dc.subject | bipyridine | |
dc.title | Reactivity studies of eta sup (6)-p-cymene ruthenium(II) carboxylato complexes towards azide some neutral ligands | |
dc.type | Journal Article | |